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What is the pH of a buffer solution prepared by dissolving 0.075 moles of the weak base, aniline (C6H5NH2), and 0.045 moles of a salt of its conjugate acid, anilinium chloride (C6H5NH3Cl), in a total buffer volume of 1.00 liters?  

Initial pH of buffer solution is:

What will the pH be after 0.012 moles of HNO3 are added?  This addition does not change the total volume of the solution. 

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