CHEM1101 Study Guide - Midterm Guide: Food Energy, Electrochemistry, Thermochemistry

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Thermodynamics and Electrochemistry
Energy
• Eegis the ailit to do ok o tasfe heat. –Energy used to cause an object that has
mass to move is called work. Energy used to cause the temperature of an object to rise is
called heat.
• This setio is about thermodynamics, which is the study of energy transformations, and
thermochemistry, which applies the field to chemical reactions, specifically.
Units of Energy
The SI unit of energy is the joule (J):
An older, non-SI unit is still in widespread use, the calorie (cal):
1 cal = 4.184 J
(Note: this is not the same as the calorie of foods; the food calorie is
1 kcal!)
Definitions: System and Surroundings
• The sste iludes the oleules e at to stud hee, the
hydrogen and oxygen molecules).
• The suoudigs ae eethig else hee, the lide ad pisto >>>
Definitions: Work
• Eeg used to oe a ojet oe soe distae is ok:
•  = F  d hee  is ok, F is the foe, ad d is the distae oe hih the foe is
exerted.
Heat
• Eeg a also e tasfeed as heat.
• Heat flos fo ae ojets to oole ojets.
• Heat is ot a thig. It is a poess. • Heat is ot a sustae otaied i a ojet.
First Law of Thermodynamics
• Eeg is eithe eated o destroyed.
• I othe ods, the total eeg of the uiese is a ostat; if the sste loses eeg, it
must be gained by the surroundings, and vice versa.
Internal Energy
The internal energy of a system is the sum of all kinetic and potential energies of all
components of the system; we call it E.
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