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23 Mar 2011
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Chapter 7: Alkenes and Alkynes I
Elimination of Alkyl Halides
•

• 

• 
•! 
•!"
•!#$%&"'&"'&('(&")
o&*+

•,+
•-+
The E2 Reaction
•./0/0
•12  +
*

•3 +"

The E1 Reaction
•3


•322

•-4-
How to Determine Whether Substitution or Elimination is Favored
•4,,
o!

o5 2

o5+2

o64
2 substitution  

o44 2  
elimination 

o34 2 
4,elimination


o3
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
o47!'(
2
o!6727
*$(",+)
$,) + "8 &,+
7!+29+4+
$4,)
•4--
o- 
 

o4--
o92  
,
-4-
Introduction
•  +

•3
•

•3
The (E)-(Z) System for Designating Alkene Diastereomers
•$)+$:)4*
  

o5

o9
2$:)
o9
2$)
Relative Stabilities of Alkenes
• 
•4

•"
•32
•;$)2<
$==/=0 =
=)
•3*

Synthesis of Alkenes via Elimination Reactions
•7
o"
o
Dehydrohalogenation of Alkyl Halides
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