CHM247H1 Chapter Notes - Chapter 10: Halocarbon, Allyl Group, Markovnikov'S Rule

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13 Mar 2014
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Organohalides: organohalide: a compound that contains one or more halogen atoms bonded to carbon, a large variety of organohalides are known. The halogen might be bonded to an alkynyl group (c c-x), a vinylic group (c=c-x), an aromatic ring (ar-x), or an alkyl group: alkyl halides: a compound with a halogen atom bonded to a saturated, sp3-hybridized carbon atom. 10. 1 names and properties of alkyl halides: named as haloalkanes, step 1: find longest chain, and name it as the parent. Step 2: number the carbons of the parent chain beginning at the end nearer the first substituent, whether alkyl or halo. Therefore bond strength weakens as you go down the periodic table: halogens are often more electronegative than carbon. This implies that the alkyl halide should behave as an electrophile in polar reactions. 10. 2 preparing alkyl halides from alkanes: radical halogenation: simple alkyl halides can sometimes be prepared from a reaction of an alkane with cl2 or.

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