CHEM 2021 Chapter Notes - Chapter 18: Acyl Halide, Ozonolysis, Aldehyde

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Chapter 18: classes of carbonyl compounds, c o bond is shorter, stronger, and more polar than c c bond in alkenes, common names: Number the chain so that the carbonyl carbon has the lowest number. Cyclic ketones: the carbonyl carbon is assigned the number 1: when the compound has a carbonyl and a double bond, the carbonyl takes precedence. Aldehyde nomenclature: the aldehyde carbon is number 1. But lower boiling point than alcohols because they cannot hydrogen bond to each other: synthesis of ketones from 2 alcohols using grignard, oxidation of primary alcohols to aldehydes, ozonolysis of alkenes, friedal-crafts ketone synthesis: Chapter 18: hydration of alkynes, hydroboration-oxidation of alkynes, synthesis of ketones from carboxylic acids, ketones and aldehydes from nitriles, reduction of nitriles, hydration of ketones and aldehydes, cyanohydrin formation. Addition (-cn), protonation (use hcn so -cn leaves) Chapter 18: acetal formation, oxidation of aldehydes to carboxylic acids. Protonation (h+), elimination (h2o leaves), addition (ch3oh), deprotonation (ch3oh)

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