BCHM 3P01 Lecture Notes - Reduction Potential, Electronegativity, Nicotinamide Adenine Dinucleotide

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This e value is like an electronegativity value- the ability for a molecule to pick up or drop off electrons. We can measure eo" (redox potential at std conditions ph 7, 1m, in v) The redox potential is how much does it want an electron! Measuring redox potential is essentially the voltage between two half reactions. Ok, remember redox potential is how much does it want an electron! We are making things that want to give off electrons (cofactors) so they give them away to oxygen which wants to get the electrons, this couples to release of protons which drives. We write the reactions in terms of reductions. Water will be more likely accept electrons from nadh. O2 /h2o e is +ve, e acceptor left->right. Nadh -> nad, -ve, so e donor right -> left. Notes: the values should be looked up in table for standard eo". Also, write out in the direction of full reaction.

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