CHM 2353 Lecture Notes - Lecture 7: Icosahedron, Improper Rotation, Oxidation State

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Oxidation numbers: hypothetical numbers assigned to an individual atom or ion present in a substance. Always reported for one individual atom or ion, not for groups of atoms or ions. Rule 1: oxidation number for an atom in its elemental form is always zero. Only one kind of neutral atom is present. Rule 2: the oxidation number of a monoatomic ion is the charge of the ion. Rule 3: all group 1a metals are +1. Rule 4: all groups 2a metals are +2. Rule 5: hydrogen is +1 when bonded to a nonmetal and -1 when bonded to a metal. Rule 6: oxygen is -2 (except when it combines with f), -1 in peroxides (o2-, h2o2), -1/2 in super oxides (o2-) Rule 8: the sum of the oxidations numbers of all atoms (or ions) in a neutral compound is 0.

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