CHMA11H3 Lecture Notes - Lecture 13: Solubility Equilibrium, Supersaturation, Dynamic Equilibrium

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erinsea-lion742

5 Feb 2019

School

UTSC

Department

Chemistry

Course

CHMA11H3

Professor

Nirusha Thavarajah, Scott M. Ballantyne, Ruby May Sullan

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CHMA11H3 Lecture Notes - Lecture 12: Lewis Acids And Bases, Oxoacid, Electronegativity

CHMA11H3 Lecture Notes - Lecture 13: Solubility Equilibrium, Supersaturation, Dynamic Equilibrium

CHMA11H3 Lecture Notes - Lecture 14: Sodium Acetate, Conjugate Acid, Sodium Hydroxide

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We characterize solubility with a concept referred to as solubility product constant, or. Ksp: example scenario, caf2 (s) ca+2 + 2 f, ksp = [ ca+2 ] [f- ]2, evaluating ksp values, smaller ksp values are used to denote reactions that are low in solubility. Indicates that the solution has no more capacity to dissolve solute: larger ksp values are used to denote reactions that are high in solubility. Indicates that the solution has more capacity to dissolve solute: we are only able to compare ksp values when the compared reactions have the same number of dissolved ions, eg: cannot compare the ksp values between. Mg(oh)2 and feco3: mg(oh)2 will dissolve to form 3 dissolved ions where are feco3 will only form 2 dissolved ions, therefore we cannot directly compare the. Ksp values: we use ice tables in order to find solubilizes.

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Experiment 10 Colligative Properties Introduction A pinch of wa make boiling water hotter. A handful will clear the snow from your steps. Every day we the physical properties of materials around us, but often don't know why we use these particular s or what chemistry is involved. Modifying the temperature of phase changes, by adding a second chemical to the pure solvent are examples of manipulating the Colligative Properties of a solution. this lab, we will study how varying the concentration and type of a salt affects the point of a solution. Colligative properties are properties of a solution containing 2 or more components. Typically, the primary is the solvent and the other called the such as color or hardness, properties depend on the number of particles of astute in the not the identity of the In many cases, the rokute will determine the number of solute particles (degree of ionization, solubility, etc,) in the solvent, but a colligative property does not depend upon the nature of the particles. Two colligative properties commonly encountered are boiling point elevation and freezing point depression (the temperature of of a is lower than of pure solvent). We will be studying boiling point elevation in this Most of the previous work that you have done with solutions has involved units of molarity, M, or moles of solute per liter of solution. Boiling point elevation calculations (as well as those for freezing point depression) or moles of solute per kilogram of solvent. boili change of temperature. When the temperature of a solution changes, the volume of the solution also changes. Since molarity depends on a change in wil the solution's molarity. Molality depends on the mass of the solvent. and thus is independent of temperature. n't Hoff Factor salt into and the of moles inorganic salts in an aque the based on the addition of the number dissociates, the total number of particles in the solution will be of cations and anions produced from the dissociation. Thus; Nacion Na Choaa (2moles of particles) Cacbrs Ca +2ch (3moles of particles) The quantity of particles produced per mole of solute is called the van'tHoff factor and is given the symbol, i, If 1 mole of sodium chloride were completely dissociated, iwould be 2. This theory works very well for dilute solutions and non-electrolytes (i 1, no dissociation at all since nonelectrolytes not ionize), For does not always apply to more concentrated solutions. Thus, when there are a large number of particles in a solution, they have a tendency to recombine as the salt and you don't get 100% dissociation. example, at a NaCl concentration of 0.1M, iwill be 1.81 (90% dissociation) rather than 2 (100%). Boiling Point Elevation solute causes the solution to boil at a higher When a solution is heated, the presence of a non-volatile point of the pure liquid and the temperature than the pure The difference between the boiling boiling point of the solution is: 169

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BAEDitemViewlassignmentProblemiD-830644918offset next 121C1 12 Introduction to Solutility and Solution Formation troduction to Solubility and Solution Formation arning Goal understand the solubility of a solute in a solvent, the dissoltion p peocess, and the properties that afect the rate of dissoluÅ¡on ocess, and the properties that affed the rate of cola has a certain amount of carbon dioxide dissolved in t The cola is theretore olecular level, the dissolution process involves breaking intermolecular forces of aty action rious parameters, such as temperature, pressure, the nature of the solute, and the r example an incresse in temperature may increase the rate of dissoludon for solutions hwolving solds an example of a solution of gas in waler. The carbon daxide gas is the solute and it is diessved in water,which is nature of the solvent One can increase or decrease the solubility of solute by changing hese parameters e f the solvere At the among the solute molecules and forming new ones with the solvent moleciles The solublty af a solute in a salent depend art A The properties of a solute and its solubility in liquid solvents A solution is a homogenous mixture of solute and solvent There are diHarent types of soluions. A carbonated drink ia an example of a solution where the solute is a gas and ths saveet is a iquid Sugar crystas a in water is an example of a solution where the solute is a solid and the solvent is liquid Aceic acid is miscible in water, forming a solution commonly known as vinegar ln this case both the solure and the sohen iquids The solubility of solute in a solvent depends on various parsmeters, such as temperature pressura, tha nature of the solute, and the nature of the salvent Considaring thesa paranters iderdfy the ts correct for the solublity of a solute in a solvent Check all that apply Hints Table salt dissolves in water to form a solution Zinc sullate is soluble in water Gases are readly soluble in water t higher tamperatures Carbon dioxide gas will be more soluble in water when the partial pressure is high Propanol and heptane are miacible Dei My Awers Give Up

CHMA11H3 Lecture Notes - Lecture 13: Solubility Equilibrium, Supersaturation, Dynamic Equilibrium

CHMA11H3 Lecture Notes - Lecture 12: Lewis Acids And Bases, Oxoacid, Electronegativity

CHMA11H3 Lecture Notes - Lecture 13: Solubility Equilibrium, Supersaturation, Dynamic Equilibrium

CHMA11H3 Lecture Notes - Lecture 14: Sodium Acetate, Conjugate Acid, Sodium Hydroxide

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