BICH 410 Lecture Notes - Lecture 2: Degree Symbol, Stoichiometry, Endergonic Reaction

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1 Sep 2016
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Spontaneous reaction (exergonic) - going from high to low energy products. Non-spontaneous reaction (endergonic) - going from low energy to high energy products. Neither h nor s alone is suf cient to determine whether a reaction is spontaneous or not. Free energy change is based off initial concentrations of the products and reactants. A constant term dependent on the reaction taking place. A variable term based on the concentration of both the reactants and products, the stoichiometry of the reaction (amount of moles), and the temperature. Products over reactants - with amount of moles for. Standard states apply to only one de ned set of condition: Occur at a speci c (constant) temperature ( 298k ) Standard states are also denoted by the degree sign - . The composition of a reacting system will continue to change until equilibrium is reached. The mixture of reactants and products changes affecting the free energy of the reaction until equilibrium is reached.

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