CHM 2120 Study Guide - Alkyne, Meta-Chloroperoxybenzoic Acid, Cyclopentanone

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4 Dec 2014
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Note: wittig and baeyer-villiger reactions will be covered at the end of the course. Questions 9, 10, and 13 pertain to those reactions: provide names for the following compounds a) b) O: draw the structure corresponding to the following names: (e)-2-butenal, 2-ethenylcyclohexanone, 4-oxohexanal, the benzyl carbocation, 1-phenylethanone (acetophenone, give the product of the following reactions, explain, using a mechanism, why the product from parts i and ii are different. Explain: how could you synthesize the following deuterium-labeled compound from benzene (note: d2o is readily available)? (remember: d = 2h, an isotope of 1h) D: give the products of the following reactions: O: draw a mechanism for the following transformations and name the key intermediates: a) 4: give the product of the following process of the reactant shown with rco3h (i. e. mcpba) and give the mechanism for the reaction in part a). a)

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