CHEM 281 Chapter Notes - Chapter 3: Cycloalkane, Substituent, Chemical Formula

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Chapter 3 notes part 5: an introduction to organic compounds: systematic names for branched substituents are obtained by numbering the alkyl substituent starting at the carbon attached to the parent hydrocarbon. This means that the carbon attached to the parent hydrocarbon is always the number-1 carbon of the substituent. You must also learn common names because they are so entrenched in chemists" vocabularies that they are widely used in scientific conversation and are often found in the literature. Look at the systematic names (the ones written in blue) for the isomeric hexanes and isomeric heptanes shown on p. 91 to make sure you understand how they are constructed. Cycloalkanes are alkanes with their carbon atoms arranged in a ring. Cycloalkanes are named by adding the prefix cyclo to the alkane name that signifies the number of carbons in the ring. Cycloalkanes are generally written as skeletal structures.

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