NUTR 3210 Lecture Notes - Lecture 5: Ribose, Cellulose, Haworth Projection
Document Summary
Next couple of classes : classification & structure, digestion & function, metabolic pathways, impact on health. Complex: oligosaccharides, polysaccharides, homo- & hetero-polysaccharides, glycogen (animal, starch & cellulose (plant, all cho have a h:o ratio of 2:1. Biological systems are stereospecific stereospecific: same molecular formula and sequence, but differ in. Diastereomers (not a mirror: chiral carbon. A carbon with four different atoms or groups. Stereoisomerism: chiral carbon, fischer projection, exist in two forms: d vs. l. The number of stereoisomers for a molecule = 2n (where n = # chiral carbons) D-monosaccharides are nutritionally more important because digestive enzymes are stereospecific for d sugars. Same rules apply for hemiacetal and hemiketal sugars. Recap for cho nomenclature: anomeric vs. chiral carbon. Chiral carbon = 4 different atoms / groups: d vs. l configuration. D confirmation is nutritionally more important: alpha or beta configuration of hemiacetal or hemiketal group. Has -oh group on anomeric carbon pointing up: fischer projection haworth model.