CHM136H1 Lecture Notes - Lecture 2: Covalent Bond, Fluorine, Electronegativity

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25 Aug 2021
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CHM136H1 Full Course Notes
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In polar covalent bonds, electrons are not shared equally due to a difference in electronegatively between the atoms. Fluorine is more electronegative, so it hogs electrons. This can be represented by using partial charges, or using crossed arrow: cross (plus sign) is on partial positive atom. In organic chemistry, polar covalent bonds allow reaction to happen. If we only had symmetrical, non-polar covalent bonds is it non-reactive: most reactions would not occur without en differences in bonds. Electronegativity: intrinsic ability of an atom to attract shared electrons in a covalent bond. Other high electronegative atoms are cl, br, o, n, c, h. Electronegativity between atoms can be used to determine type of bond. Colours indicate electron-rich (red) and electron-poor (blue) regions. In methanal ch3 is non-polar and oh is polar: c-o bond is polar (en difference is 1, o is more electronegative so more electron density around o, o has more electrons, so c has partial positive charge.

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