CHEM 110 Chapter Notes - Chapter 21: Electrophilic Addition, Sigma Bond, Organic Reactions

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CHEM 110 Full Course Notes
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CHEM 110 Full Course Notes
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Chapter 21: some important classes of organic reactions. Types of organic reactions: r- refers to a general organic group attached to one of the atoms shown, usually an alkyl group, a saturated hydrocarbon group with one bond available to link to another atom. H2o: nucleophilicity and basicity decrease across a period (ch3, when different nucleophilic atoms, size of atoms must be considered; if atoms very. Better than f-) different in size, both polarizability and solvent effects must be considered: polarizability: ease with which each electron can be delocalized over surface of atom. Larger ions (i-) have more loosely held electrons and so more polarizable than smaller (f-) Larger ions & more basic more likely act as a nucleophile: solvent effect (1) polar protic solvents: (have o-h, n-h or s-h bonds, like methanol & water) can form hydrogen bonds and solvate both cations and anions. Smaller ions, solvent shell held more tighly so more stabilizing, thus anion is less nucleophilic.

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